Catholicism came first, Orthodoxy came second, then Protestantism came third. Because Protestantism formed due to breaking away from Catholicism, you won't find their reasons for breaking away based in Orthodoxy. But given your query about the matter of supreme authority, that in itself shows why Protestantism is distinct from both. The history of authority prior to Protestantism needs to be grasped, and then it should be clear where radical differences lie in that area.
"The pope is the religious leader of Catholics worldwide whereas the
Eastern Orthodox Churches comprise several groups, self governing,
including the ancient Patriarchates of Antioch, Alexandria, Jerusalem
and Constantinople, and the Churches of Greece, Cyprus and Sinai.
Patriarchs are their leaders.
From the fourth century the Church of Constantinople – as the Church
of the new capital of the Roman (later Byzantine) Empire – ranked
second in honour to the Church of Rome, and its leader, or Patriarch,
came to be given the title Ecumenical but most of the various groups
within Eastern Orthodoxy have Patriarchs.
The Orthodox Church is based upon decrees and dogmas of various
ancient Councils before the division of Eastern and Western
Christians. There are seven ancient Councils that both Catholics and
Orthodox are agreed upon, but after 787 AD, a split arose. The Eastern
Church found unacceptable later dogmatic definitions made by the Roman
Catholic Church about the Immaculate Conception and Bodily Assumption
of the Blessed Virgin Mary, and the infallibility of the Pope. There
was also later disagreement about the Western Church statements on the
meaning of Filioque (with regard to the Holy Spirit).
Hierarchy of the Orthodox community: Parishes are grouped in dioceses,
headed by a bishop. In Russia and Romania dioceses are grouped into
larger areas, presided over by a metropolitan. Church groups do have
autonomy but this usually coincides with national frontiers, except
among Orthodox members who have emigrated, for whom Church
organizations normally follow ethnic lines. The larger national
Churches are headed by patriarchs, the smaller by archbishops. The
Patriarch of Constantinople is recognized as the focus of unity of the
Orthodox Churches. The highest authority in the Orthodox Church, the
ecumenical council, has not met sine the Council of Nicaea in 787 A.D.
A Pan-Orthodox Synod may deal with practical issues in contemporary
Orthodox Church life. The Encyclopedia of World Faiths, pp 81-86,
Bishop & Darton (Macdonald Orbis, 1987)
The Orthodox respect the pope but as they do not consider his doctrinal statements to be infallible, they will not go along with anything any pope says that does not already conform to the first, early seven Councils. Protestants likewise do not consider papal statements to be infallible, but they don't go by various Councils to determine matters. They use the Bible.
Protestantism agrees with various doctrines established at various Councils but that's only because they are shown to be biblical. It is the inspired word of God - the Bible - that Protestants take as their rule of faith and authority. If it cannot be proven from the holy Scriptures, then they will not go by what any pope or patriarch says (or, they shouldn't!) That seems to be the core difference to me, a Protestant, between both Catholicism and Orthodoxy.