I mean, there could be thousands of Orthodox Christians at this moment praying to, say, Saint Blessed Xenia of St. Petersburg, and there could probably be even more of Catholic Christians praying right now to, say, saint Patrick, let alone Mother Mary. Does that mean that all those saints have the All-knowing God's ability to hear all of those praying to them, distinguish their prayers one from another, and later adequately act on each one of them accordingly?
Time has no meaning in heaven, there is probably a more precise Thomistic answer for this question bit that should suffice. If time is meaningless then "at the same time" is meaningless. I'll get confused if I write any more about that.
We not only believe that the saints can hear and deliver our prayers to God. We believe all the angels and all the saints are present at every Mass.
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The answer is no. Recall first of all that prayer is not necessarily audible words, and secondly, the means by which prayers 'rise like incense before the throne of God' is never entirely clear. If we take for instance the issue of God hearing prayer, there are multiple ways in which the prayer could be received. To take two, the first is that God knew before the foundation of the world what would be prayed, though he himself did not make it so. The second is that through the Spirit he fills all things, and thus knows the words that are going to be prayed before they are formed into words.
We who venerate and ask for intercession of the saints believe that they dwell in God, so while it is not impossible that they can hear and interpret multiple 'messages' at the same time this does not seem to be an issue raised nor a description used. The saints live in the power and energy of the Divinity; they simply do what is given for them to do. They hear us through God to begin with.